Ferrocene piano-stool isocyanide complexes ([CpFeL3]+, Cp= η5-C5H5, L=benzyl isocyanide (1), 4-methoxyphenyl isocyanide (2), 2-Naphthyl isocyanide (3), and p-Toluenesulfonylmethyl isocyanide (4)) are formed by chemical oxidation of ferrocene in the presence of a stoichiometric amount of isocyanide ligand (1:3). The complexes are characterized by LC-Mass spectrometry, and routine spectroscopic methods (IR, 1HNMR, 13CNMR, and UV-Vis).

Synthesis and characterization of select ferrocene piano-stool isocyanide complexes

Macromolecular Chemistry: The Second Century

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ACS Spring 2020 National Meeting & Expo

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