<i>N</i>-Aminopyridinium ylides are utilized as monodentate directing groups for C–H bond functionalization with first-row transition metals. Reaction of the ylides with compounds containing carbon–carbon multiple bonds as well as other reagents will be reported. Preliminary mechanistic studies will be presented as well.

<i>N</i>-aminopyridinium ylide-directed C–H bond functionalization

Macromolecular Chemistry: The Second Century

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ACS Spring 2020 National Meeting & Expo

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N-aminopyridinium ylide-directed C–H bond functionalization