Lanthanides are particularly well-suited for the construction of single-molecule magnets due to their large magnetic moments and high magnetic anisotropy. Exceedingly high spin-reversal barriers and blocking temperatures can be attained by employing lanthanide ions that have intrinsically large orbital angular momentum such as Tb3+, Dy3+ and Er3+. A common strategy to design mononuclear lanthanide single-molecule magnets consists of pairing the ligand field symmetry with the anisotropic electron density distribution of the maximal MJ state. Here, we will present new mononuclear lanthanide complexes containing redox-active ligands that show slow magnetic relaxation.

Mononuclear lanthanide single-molecule magnets containing redox-active ligands

Macromolecular Chemistry: The Second Century

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ACS Spring 2020 National Meeting & Expo

The official archive and repository for all ACS Meetings & Expositions abstracts and select posters or presentations.