The synthesis of nickel complexes with dithiolate derivatives of 3-hydroxy-1,5-diazacyclooctane and 3,7-dihydroxy-1,5-diazacyclooctane will be discussed. The complexes will be characterized in the solid-state and in solution. The effects of pH on the structure and stability of the complexes will be shown. Preliminary reactivity studies of these metal complexes towards oxygenating species and alkylating agents in the presence of the pendant hydroxyl group will also be presented.

Nickel complexes with N2OS2 and N2O2S2 ligands

245th National Meeting (2013)

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