Diallycarbamyl chloride has found use in patented herbicidal applications of novel tetrazolinones and as a useful precursor in the formation of many pharmaceutically useful inhibiting compounds. The specific rates of solvolysis of diallylcarbamyl chloride were determined at 25.0�C in solvents of varying nucleophilcity and ionizing power. In this presentation we will also compare the pseudo first order rates obtained for diallylcarbamyl chloride to those obtained for the previously studied alkyl and aryl carbamoyl chlorides. We will show that the mesomeric effect of the allyl groups in R2NCOCl dominate the rates of reaction. This project is supported, in part, by the Delaware INBRE and EPSCoR programs - supported by grants from the National Center for Research Resources-NCRR (5P20RR016472-12) and the National Institute of General Medical Sciences - NIGMS (8 P20 GM103446-12) from the National Institutes of Health (NIH); a National Science Foundation (NSF) Delaware EPSCoR grant EPS-0814251; and a NSF ARI-R2 grant 0960503.

Solvolyses of diallylcarbamyl chloride

245th National Meeting (2013)

The official archive and repository for all ACS Meetings & Expositions abstracts and select posters or presentations.