The synthesis of the V(V) complex of mercaptomethylpropyl-1,5-diazacycloheptane is reported. Non-aqueous techniques were utilized to prepare the V(V) complex due to the tendency of V(V) to undergo reduction in the presence of thiolates. The characterization of the complexes in the solid-state and in solution will also be presented.

Synthesis and structure of a new vanadium(V) thiolate complex

247th National Meeting (2014)

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