Dithiocarbamate ligands with simple alkyl or aryl substituents are well known in coordination chemistry. Less common are dithiocarbamates derived from significantly electron-withdrawing or electron-donating amines. A series of iron, cobalt, and nickel dithiocarbamate complexes with electronically varied substituents have been prepared and characterized. Synthetic details, spectroscopic characterization, and magnetic susceptibility measurements will be presented.

Iron, cobalt, and nickel complexes of electronically varied dithiocarbamate ligands

247th National Meeting (2014)

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