The production of hydrogen from water with semiconductor photocatalysts is often promoted by the addition of a small amount of a metal to their surfaces.  It is commonly believed that the resulting enhancement in catalytic activity is due to a fast transfer of the excited electrons generated by photon absorption from the semiconductor to the metal, a step that prevents de-excitation back to the ground electronic state.  Here we provide several pieces of evidence to argue against this mechanism.  An alternative explanation is advanced where the metal acts as a catalyst for the recombination of the hydrogen atoms made via the reduction of protons on the surface of the semiconductor instead.  New metal@TiO2 yolk-shell nanomaterials were conceived to test our hypothesis, and the preparation and characterization of those will be discussed in this presentation as well.

Electron trap or atomic hydrogen recombination catalyst? The role of metals in photocatalysis revisited

248th National Meeting (2014)

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