p-Conjugated molecules are attracted much attentions from a viewpoint of organic electronic devices, such as electroluminescent materials, field-effect transistors, and solar-cells. Because incorporation of boron and nitrogen atoms into carbon-based p-conjugated systems changes their electronic properties drastically, the B,N-containing p-conjugated systems are expected to be novel functional materials. In this research, we focused on 9-bora-10-azaanthracene framework bearing transformable functional groups and Lewis complexes of borabenzene and pyridine derivatives. Here, we report synthesis of novel B,N-containing p-conjugated molecules, such as the 9-bora-10azaanthracene bearing N-BCl2 and B-Cl groups and borabenzene-Lewis base adducts.

Synthesis of p-conjugated compounds using the transformation of 9-bora-10-azaanthracene and borabenzene-Lewis base adducts

248th National Meeting (2014)

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