We have reported several powerful bifunctional organocatalysts for the enantioselective aza-Morita-Baylis-Hillman (aza-MBH) reaction of enones and imines.1 In this presentation the acid-base organocatalysis for the domino reactions based on the aza-MBH reaction (eq. 1),2 and the formal [n+2] cycloaddition of ketimines with allenoates (eqs. 2 and 3) 3, 4 will be discussed.

Enantioselective organocatalyzed domino process based on aza-Morita-Baylis-Hillman-type (aza-MBH) reaction

248th National Meeting (2014)

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