Pincer iridium complexes with sterically undemanding alkyl and alkoxide groups on the P atoms have been prepared.   The reduced steric profile at the Ir center leads to significant changes in reactivity.  Application  of these complexes in hydrogenation/deoxygenation  of various substrates will be described.<br/>

Hydrogenolyis reactions catalyzed by iridium pincer complexes

249th National Meeting (2015)

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