Interest the study of dinitrosyl iron compounds (DNICs) has grown significantly due to their biological relevance which may include the ability to serve as entities for the storage and transport of nitric oxide. Reactions with DNICs may take place at the iron center, at the bound nitrosyl ligands or at ancillary ligands. We have prepared dinitrosyl iron complexes with the general formula Fe(NO)2LL' (L and L' = phosphine donor ligands) from the reactions of Fe(NO)2(CO)2 and phosphine donor ligands. We have investigated their reaction with selected nucleophiles. The products have been characterized by a variety of instrumental methods including infrared spectroscopy and 31P{1H} NMR spectroscopy.

Addition reactions of some dinitrosyl iron diphosphine complexes

253rd National Meeting (2017)

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