Hydrazines remain of active interest for their application as rocket monoprollents. In this role, their interaction and stability with various metals is a key property. This work utilizes a variety of substituted hydrazines (N-methyl, N,N-dimethyl, N,N’-dimethyl, N-phenyl, N,N-diphenyl, N,N’-diphenyl, N-ethoxy) with the Ru(PPh3)2Cl2 fragment to investigate the influence of hydrazine substitution on the geometrical parameters, including coordination mode, of the bonding to ruthenium. Complexes were fully characterized by single-crystal XRD as well NMR, FTIR, and UV-vis spectroscopy.

Synthesis and characterization of ruthenium-hydrazine complexes

256th National Meeting (2018)

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