Non-innocent ligands binded transition metals catalysis has received tremendous attention during the past decade. This strategy allows the reaction go through a single electron process by allowing the electron or positive charge entering the ligands’ p system without messing up the coordination patterns, which largely enhanced the metal reactivity towards challenge transformations. Herein we reported a new type of triazole based-tridentate non-innocent ligand, which can be easily synthetized through gold-catalyzed A<sup>3</sup> coupling reaction. With this strategy in hand, various of 2-substituted tridentate ligands and their complexes has been synthesized. Their metals complex such as Mn, Ni, and Fe, were prepared and well characterized, along with their activities in hydroboration reaction.<br/>

Novel design and preparation of a triazole-based tridentate ligand

2019 Spring National Meeting

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