Polynuclear metal assemblies in enzyme active sites, at metal surfaces, and impregnated into porous solids can catalyze bond forming reactions involving small molecules to afford higher value chemicals (<i>e.g.</i>, water oxidation and Fischer-Tropsch chemistry). Here, we will detail our recent advances in the developing multimetallic complexes employing late 3<i>d</i> metals to effect bond forming reactions between small molecules observed in the aforementioned systems. Our results evidence and accesses the potential of designed multimetallic architectures to mimic the controlled redox cooperativity of more complex systems.

Let's get together! Making bonds between small molecules at multimetallic centers

2019 Fall National Meeting

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