Complexes [MII(CN-B(C6F5)3)4]2- (M = Ni, Pd, Pt) were synthesized and characterized by X-ray crystal structure analysis, UV-visible spectroscopy, IR spectroscopy, and voltammetry. The PtII/Icouple in PtII(CN-B(C6F5)3)4]2- is electrochemically reversibile. Excited-state assignments and orbital orderings were based on TD-DFT and CASSCF-NEVPT2 calculations.

Electronic structures, spectroscopy and electrochemistry of square planar [MII(CN-B(C6F5)3)4]2-(M = Ni, Pd, Pt) complexes

ACS Spring 2022

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