Sulfur-fluoride exchange (SuFEx) chemistry is emerging as a promising synthetic tool in chemical biology, material science, and synthetic chemistry. In synthesis, sulfur(IV) or (VI) fluorides show unique promise as synthons in organic chemistry due theirstabilityversus other sulfur(VI) halogen analogues. Key to the adoption of SuFEx chemistry is the development of efficient modes to synthesize and react sulfur fluorides. This presentation will focus on our on-going work highlighting recent efforts toward new fluorosulfurylation strategies of organic molecules in addition to the development of new methods to unlock their reactivity.

Unlocking fluorine: Activation of sulfur(VI) fluorides for new sulfur-fluorine exchange (SuFEx) reactions

Fall 2022 abstracts, posters, and presentations will launch in mid-September.

ACS Fall 2022

The official archive and repository for all ACS Meetings & Expositions abstracts and select posters or presentations.