The introduction of fluxional building blocks into polymers imparts physical changes to macromolecular architecture and structure. Physical properties can be tuned in solution and in the bulk by including bullvalene, a fluxional hydrocarbon cage that functions as a self-contained dynamic combinatoral library, into soft materials. In this talk, recent work from my laboratory on the synthesis and characterization of bullvalene-containing in dynamic macromolecules will be discussed.

Advances in dynamic macromolcules derived from bullvalene building blocks

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ACS Spring 2023

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