Iron complexes [BIAN]Fe(η<sup>6</sup>-toluene) and [BIAN]FeCl<sub>2</sub> (BIAN = bis(2,6-diisopropylaniline)acenaphthene) were found to be viable catalysts for the regioselective hydroboration of alkynes and alkenes. The hydroboration of alkynes and alkenes in the presence of HBpin and an activator at 70 °C afforded linear vinyl and alkyl boronic esters, respectively. Selectivity up to 98% was observed for alkyl boronic esters and exclusive formation of trans product was observed for vinyl boronic esters. These results, along with preliminary mechanistic studies will be discussed.

Hydroboration of alkenes and alkynes employing earth-abundant metal catalysts

Macromolecular Chemistry: The Second Century

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ACS Spring 2020 National Meeting & Expo

The official archive and repository for all ACS Meetings & Expositions abstracts and select posters or presentations.