When reduced in size to the nanoscale, materials express compelling new phenomena. For example, a single layer abstracted from graphite leads to fantastic new properties in graphene, or a nanocrystal of gold takes on new optical properties as a nanoparticle. Making materials very small or very thin has been an easy way to prepare exciting new materials—for example, the 2D transition metal dichalcogenides (TMDCs) have a long history of investigation prior to the recent interest in their monolayers for applications in photovoltaics, electrocatalysts, and spintronic materials. 2D phases have been uncovered for a number of elements and binary semiconductors, although many compounds do not share the same propensity to form 2D structures. Here we discuss inorganic coordination polymers as hybrid materials that combine a self-assembling layered structure with well-defined, quantum-confined inorganic phases, and we examine their light-matter interactions. The role of intermolecular forces and molecular geometry on the inorganic phases are considered in the context of transitions between 1D, 2D, and 3D coordination polymer systems.<br/>

Metal-organic chalcogenolate coordination polymers as a nanotechnology platform

Macromolecular Chemistry: The Second Century

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ACS Spring 2020 National Meeting & Expo

The official archive and repository for all ACS Meetings & Expositions abstracts and select posters or presentations.