<br/>Transition-metal mediated bond cleavage and formation has made a great contribution in synthetic organic chemistry. A metal-ligand cooperativity often plays essential roles in the bond cleavage and formation reactions. Shvo and Casey studied the heterolytic cleavage/formation of H–H bond mediated by cyclopentadienone metal complexes with simultaneous oxidation/reduction of the central metal. Here in this presentation, this cooperativity is applied to the new type of bond cleavage/formation reactions such as C–O, C–H, and B–H Bonds.

Metal–ligand cooperative cleavage of C–O, C–H,and B–H bonds

Macromolecular Chemistry: The Second Century

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ACS Spring 2020 National Meeting & Expo

The official archive and repository for all ACS Meetings & Expositions abstracts and select posters or presentations.