Breakthrough strategies that facilitate the manufacturing of a rich variety of nanocrystals with controlled dimensions, architectures and surface chemistry are of key importance in revolutionarily advancing their use for myriad applications in energy conversion and storage. Herein, I will discuss several robust manufacturing strategies to access monodisperse 0D 1D, shish-kebab, and Janus nanocrystals by capitalizing on an array of rationally designed unimolecular star-like, bottlebrush-like, worm-like, and Janus block copolymers, respectively, as nanoreactors. These four strategies are effective and able to produce oil-soluble and water-soluble monodisperse nanocrystals, including metallic, ferroelectric, magnetic, luminescent, semiconductor, perovskite, and their core/shell structures, which represent a few examples of the kind of nanocrystals that can be produced using these techniques. The applications of these functional nanocrystals in energy conversion and storage (e.g., perovskite solar cells, LEDs, thermoelectrics, ferroelectrics, batteries, and electrocatalysis) will also be presented.

Manufacturing polymer-ligated nanocrystals via nonlinear block copolymer nanoreactors for energy conversion and storage

Macromolecular Chemistry: The Second Century

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ACS Spring 2020 National Meeting & Expo

The official archive and repository for all ACS Meetings & Expositions abstracts and select posters or presentations.