Stable organic radicals are promising building blocks for multifunctional molecular materials owing to their unique physical properties. These materials can combine optical, transport and magnetic properties which can be fine-tuned by making small changes to their molecular structure using organic synthesis. Control of their solid-state packing is essential to custom tailor their macroscopic properties. This requires the development of structure-activity relationships. We have recently developed a variety of synthetic routes to air- and moisture-stable benzo[<i>e</i>][1,2,4]triazinyl radicals (<i>aka</i> Blatter radicals) in an effort to identify structure-magnetism correlations. Herein, we present a magneto-structural study of the 1-(2-methoxyphenyl)-3-(phenyl)-1,4-dihydro-1,2,4-benzotriazin-4-yl radical.

Crystal structure and magnetic properties of 1-(2-Methoxyphenyl)-3-(phenyl)-1,4-dihydro-1,2,4-benzotriazin-4-yl

Macromolecular Chemistry: The Second Century

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ACS Spring 2020 National Meeting & Expo

The official archive and repository for all ACS Meetings & Expositions abstracts and select posters or presentations.