Heterostructured nanomaterials have attracted considerable interest as a paradigm for leveraging the emergence of new properties in ultrathin or nanoscaled materials for the exploitation of dissimilar functionality for the development of new applications. For example, core-shell morphologies have been exploited in nanocrystals, in hybrid coordination polymer network systems like MOFs, and recently in lateral and vertical heterostructures of 2D ultrathin materials. Especially in the case of hybrid materials, this rapid proliferation of new paradigms in material design has led to considerable opportunities for tailored material systems for specific applications, including catalysis, gas phase separations, and semiconductor devices. The particular advantage of hybrid nanostructures have attracted interest for controlling the chemical functionality and physics of a material from the bottom up. Here we present epitaxy in the homologous series of silver benzenechalcogenolates, [AgSPh], [AgSePh], and [AgTePh]. Synthetic, structural, and optoelectronic properties are examined.

Heteroepitaxy at metal-organic chalcogenolate coordination polymer interfaces

Macromolecular Chemistry: The Second Century

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ACS Spring 2020 National Meeting & Expo

The official archive and repository for all ACS Meetings & Expositions abstracts and select posters or presentations.