Here is presented a readily synthesized, PNP-ligated, iron hydride complex. We have demonstrated the ability of this molecule to activate the C-H bonds in benzene via a photo-assisted mechanism using UV light. This complex has robust thermal stability, and persists in the presence of both acids and bases. Such a system has the potential to have direct application in a number of C-H bond activation reactions. Research is currently being conducted on the potential catalytic utility of this system.

Photo-assisted, iron hydride C-H bond activation

Macromolecular Chemistry: The Second Century

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ACS Spring 2020 National Meeting & Expo

The official archive and repository for all ACS Meetings & Expositions abstracts and select posters or presentations.