The construction of hydrogen-bonded frameworks (HBFs) that express permanent porosity and functionality is challenging due to the delicateness of hydrogen bonds. We present UNAM-1, a robust 3D-HBF fully sustained by charge-assisted H-bonds between [CuIICuI12(HL)12]10- and [Me2NH2]+ units, which displays a surface area of 522 m2 g-1 and reversibly adsorbs SO2 (3.5 mmol g-1).

UNAM-1: A robust 3D-HOF with mixed valence copper and permanent porosity, capable to reversibly adsorb SO2

LatinXChem

The official archive and repository for all ACS Meetings & Expositions abstracts and select posters or presentations.