Multiple palladium-catalyzed cross couplings  with ensuing pericyclic reactions can favorably be applied towards the construction of complex carbon skeletons like those of steroids. Following the discussion of some such examples, titanium-mediated syntheses of various cyclopropylamines as well as new copper-catalyzed formations of important heterocycles such as tri- and disubstituted pyrroles will be presented.

Pd-catalyzed sequential reactions and other metal-mediated transformations for efficient organic synthesis

239th National Meeting (2010)

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