Copper-catalyzed formations of sulfur-nitrogen bonds can be carried out by a dehydrocoupling of aryl thiols with amines. The reaction gives sulfenamides or sulfonamides in air or under oxygen. Furthermore, a reaction by the combination of a palladium catalyst with a copper catalyst selectively affords sulfinamides.

Copper-catalyzed formations of sulfur-nitrogen bonds using thiols

240th National Meeting (2010)

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