Reactivity of pentavalentiodine reagents can be modulated by ligand complexation, armed with thisinformation, the reactivity of iodine nucleus was explored using differentquaternary ammonium halides and this property of pentavalent iodine reagents weresuccessfully utilize for development of mild, chemoseletive, high yieldingmethod for oxidation of sulfides to sulfoxides using three different Novelsystem IBX/TEAB, DMP/TEAB and Iodic acid/TEAB.

Studies in oxidation of sulfides using pentavalent iodine reagents

240th National Meeting (2010)

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