[Rh(PR2NR2)2](BF4) complexes, where PR2NR2 is a diphosphine ligand with pendant amines positioned to shuttle protons to and from the metal center, have been synthesized and investigated for their use in proton-coupled electrocatalytic reduction of CO2. Systematic modifications of the substituents on the ligands were made to tune these complexes for CO2 activation and reduction. Electrochemical and spectroscopic studies will be discussed.

Rhodium(I) disphosphine complexes with pendant amines for proton-coupled electrocatalytic reduction of CO<sub>2</sub>

243rd National Meeting (2012)

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Rhodium(I) disphosphine complexes with pendant amines for proton-coupled electrocatalytic reduction of CO2

Rhodium(I) disphosphine complexes with pendant amines for proton-coupled electrocatalytic reduction of CO₂