The construction of robust porous metal metalloporphyrin frameworks (MMPFs) with permanent porosity is of great interest but remains a challenge for the development of porphyrin/metalloporphyrin-based functional materials in various applications. Based on the custom-designed porphyrin ligands, a series of highly porous MMPFs have been prepared. Their permanent porosities were confirmed by gas sorption studies, and the existence of metalloporphyrin struts affords them interesting CO2 sorption behavior, highlighting their potential as a new platform for CO2 capture.

Porous metal metalloporphyrin frameworks (MMPFs) as platform for CO<sub>2</sub> capture

243rd National Meeting (2012)

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Porous metal metalloporphyrin frameworks (MMPFs) as platform for CO2 capture

Porous metal metalloporphyrin frameworks (MMPFs) as platform for CO₂ capture