Thermochemical biomass conversion to fuels and chemicals can be achieved through gasification to syngas.  The biomass derived raw syngas contains the building blocks of carbon monoxide and hydrogen as well as impurities such as tars, light hydrocarbons, and hydrogen sulfide. These impurities must be removed prior to fuel synthesis.  We used catalytic reforming to convert tars and hydrocarbons to additional syngas, which increases biomass carbon utilization.  In this work, nickel based, fluidizable tar reforming catalysts were synthesized and evaluated for tar and methane reforming performance with oak and model syngas in two types of pilot scale fluidized reactors (recirculating and recirculating regenerating).  Because  hydrogen sulfide (present in raw syngas and added to model syngas) reacts with the active nickel surface, regeneration with steam and hydrogen was required.  Pre and post catalyst characterization showed changes specific to the syngas type used.  Results of this work willl be discussed in the context of selecting the best process for pilot scale demosntration.

Producing clean syngas via catalytic reforming for fuels production

244th National Meeting (2012)

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