Metal-organic frameworks (MOFs) are an intriguing class of hybrid materials that are constructed by assembling secondary building-units (SBUs) with organic linkers. Such an approach provides the opportunity to incorporate species within the structure of MOF, facilitating specific functionality in defined framework with particular applications such as gas storage.A new class of porous, redox-active metal-organic framework materials have been synthesized by using redox-active 4,4'-bisphenol and iron-pyrazolato clusters [Fe8(�4-O)4(�2-4-R-pz)12Cl4] (R = H, CH3, Cl and CH2CH2OH) as linkers and SBUs, respectively.The characterization of these materials by TGA, XRPD and 57Fe-M�ssbauer spectroscopy and the study of their redox and gas (N2, CH4, CO2) adsorption properties will be discussed.

Redox-controlled Fe<sub>8</sub>-cluster-based metal-organic frameworks for bulk removal of CO<sub>2</sub>

244th National Meeting (2012)

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Redox-controlled Fe8-cluster-based metal-organic frameworks for bulk removal of CO2

Redox-controlled Fe₈-cluster-based metal-organic frameworks for bulk removal of CO₂