Conformational switching is an important issue to regulate the function of a molecule or a supramolecule. We have established the redox-induced conformational alteration based upon aromatic amides bearing N-phenyl-N-quinonyl group as a external stimuli responsive part. In order to expand this concept with the input and output, various types of N,N-diaryl amides were designed and synthesized. Conformational features of these N,N-diaryl amides were investigated, and external condition responsive alteration of conformational preference was revealed.

Conformational analyses and external stimuli induced conformational alteration of <i>N</i>,<i>N</i>-diaryl amides

244th National Meeting (2012)

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Conformational analyses and external stimuli induced conformational alteration of N,N-diaryl amides