Unification of Anion Relay Chemistry (ARC) with the Takeda and Hiyama palladium catalyzed cross-coupling reactions to provide aryl-aryl, alkenyl-aryl and alkenyl-alkenyl coupling products, employing easily prepared and recoverable silicon-based transfer agents, has been achieved. Investigations to optimize the silicon-based transfer agent, through structural modifications will be presented.                                                                        

In search of an optimal silicon transfer agent for cross-coupling reactions

244th National Meeting (2012)

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