Matrix-assisted Polymer Pen Lithography (PPL) induces site-specific reactions to pattern fluorescent and redox active inks with sub-micrometer scale feature sizes onto cm2 area with precise control over feature diameter, ligand density, and orientation.  This strategy demonstrates the generality of matrix-assisted PPL as a facile and reproducible tool for exploring the viability of organic transformations that are not commonly used in surface science applications. This approach also facilitates the kinetic study of force catalyzed cyclic reactions.

Matrix-assisted Polymer Pen Lithography: A new method for immobilization of bioorthogonal reactions and kinetic characterization of force catalyzed reactions

244th National Meeting (2012)

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