Utilization of nanac-based pyridine-imine and related ligands with the potential for redox non-innocent behavior will be presented. Characterizations of the complexes will feature M�ssbauer spectroscopy and X-ray crystallography among other analytical methods. Electronic structures of the molecules will be probed by calculations, and correlations with reactivity will be assessed when possible. Reactions of these complexes with small molecules, and approaches to C-C bond formation will be featured.

Recent advances in redox non-innocent ligands applied to first row transition metals

245th National Meeting (2013)

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