Preparation of molecule-based magnets have been attracting significant attention in the fields of inorganic chemistry, material chemistry and industrial chemistry. Hexacyanometalates [M(CN)x]n (M = transition metal ion) acting as building blocks have been utilized extensively in the study of the cyano-bridged Prussian Blue analogues. We are interested in synthesizing lanthanide and transition metal bimetallic complexes, and investigating their material properties and their catalytic effects. This paper here reports the synthesis, characterization and X-ray structure of [Gd(bipyO2)2(H2O)3Fe(CN)6] complex containing the cyano-bridged ligand.

Synthesis and X-ray characterization of d-f bimetallic complex

245th National Meeting (2013)

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