1,2-cis glycosidic bonds are prevalent structural motifs in biologically relevant natural products and glycoconjugates that remain difficult to access synthetically. Described in this presentation is the development of a template-directed glycosylation methods via a sequential redox process that permits the robust construction of 1,2-cis glycosidic linkages. Examples will be given in the context of �-mannoside and �-rhamnoside synthesis.

Template-directed stereoselective glycosylation via a sequential redox process

245th National Meeting (2013)

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