We have studied the cleavage of C-S and C-O bonds in a variety of esters, thioesters, and thioethers using group 10 unsaturated metal fragments. In this talk we will compare and contrast the reactivities of the metal fragments [Ni(PONOP)], [Ni(dippe)], and [Pt(dippe)]. These studies allow direct comparison of Ni0 vs. Pt0systems with different substrates.

Carbon-sulfur and carbon-oxygen bond cleavage reactions using nickel, palladium, and platinum

245th National Meeting (2013)

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