Synthetic pathways leading to formation of functional polymers with stimuli responsive properties has recently attracted a significant research interest. We present novel synthetic strategies allowing preparation of functional homo/block silicones copolymers using disodiumoxysiloxanes as precursors for the reaction. The reactions are carried out at mild experimental conditions and allow precise control over functional silicone unit distribution along the backbone of the parent polymer. Possible mechanisms of polymer formation and its effect on a final polymer composition and polydispersity are discussed.

Novel strategies for chemical synthesis of functional silicones

245th National Meeting (2013)

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