In order to synthesize macromolecular [2]rotaxanes consisting of a polymer chain as an axle component and one crown ether as a wheel component, two synthetic methods were investigated. One is the end-cap method via introduction of polymer chain to the axle end of rotaxane having a reactive group at the axle terminal. The other is the rotaxane-from method via polymerization initiated by axle-terminal group of pseudorotaxane.

Synthesis and characterization of macromolecular [2]rotaxane having polymer chain as the axle component

245th National Meeting (2013)

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