  A direct, multicomponent assembly of 1,5-enynes has been developed. The titanocene-catalyzed coupling of an aryl aldehyde, iodoalkyne, and allyl silane enables the convergent and rapid synthesis of this versatile architectural motif in good to excellent yields.

Relay redox and Lewis acid catalysis in the titanocene-catalyzed multicomponent assembly of 1,5-enynes

246th National Meeting (2013)

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