Uranyl phosphonates have displayed rich and fascinating structural chemistry; most of the structures are layered, and the metal ions are bridged by the phosphonate moiety. The structural chemistry of metal arsonates are expected to be similar to those of the metal phosphonates, but the larger ionic radius and longer As�O bond length of As(V) compared to P(V) could greatly influence their structural and physical properties. This presentation will compare results from my current studies with arsonates to past work with phosphonates.

Correlations and differences between uranium(VI) arsonates and phosphonates

246th National Meeting (2013)

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