By the application of Au(I) catalyzed B-H reduction of amine-boron complex, a challenging precursor for azaborine complex was synthesized very effeicently and by the DDQ oxidation, the NB heterocycles was oxidized to azaborine dirivitives with high yield. This method is improved from the troditional methodology which based on the allylic borane metathesis.

Gold(I) catalyzed boron-nitrogen heterocycles synthesis

246th National Meeting (2013)

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