Imines are important synthetic intermediates in the synthesis of substituted amines. This poster will describe the use of the Cu/azodicarboxylate catalyst system for aerobic dehydrogenation of N-protected amines to imines. The catalyst system resembles the Cu/azodicarboxylate catalyst system original developed by Marko and coworkers for alcohol oxidation (cf. Mark� et al. Adv. Inorg. Chem. 2004  56, 211�240). New insights have been obtained into aerobic reoxidation of hydrazine dicarboxylates in this study.

Aerobic oxidation of amines bonds using azodicarboxylates

246th National Meeting (2013)

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