The ionic porphyrins TPPS, TMPyP, and TTMAPP were synthesized and used in the formation of NiII and FeII complexes. Anionic M-TPPS and cationic M-TMPyP were used to form bimetallic cofacial porphyrin dimers in solution.  Bimetallic dimer couples M-TPPS/M-TMPyP were investigated for electrocatalytic behavior towards carbon dioxide activation and reduction.

Bimetallic catalysts supported by ionic porphyrins:  Activity of cofacial porphyrin dimer towards CO<sub>2</sub> reduction

247th National Meeting (2014)

The official archive and repository for all ACS Meetings & Expositions abstracts and select posters or presentations.

Bimetallic catalysts supported by ionic porphyrins: Activity of cofacial porphyrin dimer towards CO2 reduction

Bimetallic catalysts supported by ionic porphyrins: Activity of cofacial porphyrin dimer towards CO₂ reduction