In this talk the ability of clusters such as [Fe4N(CO)12]1-, [Fe4C(CO)13]2- and [CuH(PPh3)]6 to behave as CO2 reduction electrocatalysts will be described. Insights into the catalytic mechanisms of formate formation will be discussed including the ability of the clusters to stabilize hydride intermediates.

Electrocatalytic reduction of CO<sub>2</sub> by metal-metal bonded clusters of iron and copper

247th National Meeting (2014)

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Electrocatalytic reduction of CO2 by metal-metal bonded clusters of iron and copper

Electrocatalytic reduction of CO₂ by metal-metal bonded clusters of iron and copper