We determined the heterogeneous spatial apportionment of functional groups in a series of metal-organic frameworks containing BDC (1,4-benzenedicarboxylate) linkers with different functional groups. Our analysis discern between random, alternating, and various cluster forms of functional group apportionments. This is a first step in designing sequences of functionalities within ordered structures.

Apportionment of MOF functionalities at the nanoscale

247th National Meeting (2014)

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