The recently reported neutral, four-coordinate nitrides of vandium show the ability to insert into the hydridic E-H bond (E = B, Al, Si) to give the cooresponding V(III) amido species. These diverse complexes have been fully charecterized and shed light into the reactivity of the nucleophilic nitride moiety.

Insertion chemistry of a neutral vanadium nitride

248th National Meeting (2014)

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